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Excitations in Organic Solids$
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Vladimir Agranovich

Print publication date: 2008

Print ISBN-13: 9780199234417

Published to Oxford Scholarship Online: January 2009

DOI: 10.1093/acprof:oso/9780199234417.001.0001

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Frenkel Excitonic States in The Heitler-London Approximation

Frenkel Excitonic States in The Heitler-London Approximation

Chapter:
(p.10) 2 FRENKEL EXCITONIC STATES IN THE HEITLER-LONDON APPROXIMATION
Source:
Excitations in Organic Solids
Author(s):

Vladimir M. Agranovich

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780199234417.003.0002

This chapter discusses Frenkel excitonic states in Heitler-London approximation. The Coulomb and mechanical excitons in molecular crystals are introduced using the crystal Hamiltonian. The excitons symmetry properties are considered via group-theoretical methods. Applications to crystals of naphthalene type are given.

Keywords:   Frenkel, Coulomb and mechanical excitons, Davydov splitting, naphtalene, group theory

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