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The Chemical Bond in Inorganic Chemistry$
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I. David Brown

Print publication date: 2016

Print ISBN-13: 9780198742951

Published to Oxford Scholarship Online: November 2016

DOI: 10.1093/acprof:oso/9780198742951.001.0001

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Physical Properties of Bonds

Physical Properties of Bonds

Chapter:
(p.136) 8 Physical Properties of Bonds
Source:
The Chemical Bond in Inorganic Chemistry
Author(s):

I. David Brown

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780198742951.003.0008

In addition to their lengths and angles (Section 8.4), bonds are associated with other measurable properties such as atomic radius (Section 8.3), force constants (Section 8.5), thermal expansion (Section 8.6) and compression (Section 8.8). Corrections to the bond valence parameter, R0, are proposed for measurements made at high temperatures and pressures (Section 8.8). Although bond energy is not well defined, changes in energy close to equilibrium correlate with bond valence mismatch (Section 8.2).

Keywords:   force constant, bond energy, thermal expansion, pressure

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