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The Chemical Bond in Inorganic Chemistry$
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I. David Brown

Print publication date: 2016

Print ISBN-13: 9780198742951

Published to Oxford Scholarship Online: November 2016

DOI: 10.1093/acprof:oso/9780198742951.001.0001

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Hydrogen Bonds

Hydrogen Bonds

Chapter:
(p.76) 5 Hydrogen Bonds
Source:
The Chemical Bond in Inorganic Chemistry
Author(s):

I. David Brown

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780198742951.003.0005

The hydrogen atom has unusual but important properties (Sections 5.6–5.7) that are central to much of chemistry. The asymmetry of the hydrogen bond arises from the repulsion between the donor and acceptor anions (Section 5.2). This constraint determines the geometry of the normal hydrogen bond (Section 5.3) and indicates where shorter (Section 5.4) or longer (Section 5.5) hydrogen bonds will be found. A variety of techniques is available for determining hydrogen bond valences from the bond lengths (Section 5.8).

Keywords:   hydrogen bonds, donor, acceptor, bond valence

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