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The Chemical Bond in Inorganic Chemistry$
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I. David Brown

Print publication date: 2016

Print ISBN-13: 9780198742951

Published to Oxford Scholarship Online: November 2016

DOI: 10.1093/acprof:oso/9780198742951.001.0001

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The Bond Valence Model

The Bond Valence Model

Chapter:
(p.36) 3 The Bond Valence Model
Source:
The Chemical Bond in Inorganic Chemistry
Author(s):

I. David Brown

Publisher:
Oxford University Press
DOI:10.1093/acprof:oso/9780198742951.003.0003

The bond valence model provides the tools needed for a practical implementation of the flux theory. These include the empirical bonding strengths of atoms, i.e. Lewis acid and base strengths (Section 3.4.3) and the empirical correlation between the bond fluxes (valences) and bond lengths (Section 3.2). Other tools include the distortion theorem (Section 3.4.2), network equations (Section 3.4.4, 3.4.5), valence maps (Section 3.4.6) and bond valence vectors (Section Section 3.4.7).

Keywords:   bond valence, bonding strength, Lewis, bond lengths, distortion, valence maps

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