Aperiodic Crystals
From Modulated Phases to Quasicrystals
Janssen, Ted,
Department of Theoretical Physics, University of Nijmegen
Chapuis, Gervais,
Department of Physics, Ecole Polytechnique Federale de Lausanne
de Boissieu, Marc,
CNRS researcher, Laboratoire de Thermodynamique Physico Chimie Metallurgique, Grenoble
Print publication date: 2007
Published to Oxford Scholarship Online: September 2007 Print ISBN-13: 978-0-19-856777-6 doi:10.1093/acprof:oso/9780198567776.001.0001 |
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Abstract:
Until the 1970s, all materials studied consisted of periodic arrays of unit cells, or were amorphous. In the last decades a new class of solid state matter, called aperiodic crystals, has been found. It is a long range ordered structure, but without lattice periodicity. It is found in a wide range of materials: organic and anorganic compounds, minerals (including a substantial portion of the earths crust), and metallic alloys, under various pressures and temperatures. Because of the lack of periodicity, the usual techniques for the study of structure and physical properties no longer work, and new techniques have to be developed. This book deals with the characterization of the structure, the structure determination, and the study of the physical properties, especially dynamical and electronic properties of aperiodic crystals. The treatment is based on a description in a space with more dimensions than three, the so-called superspace. This allows us to generalise the standard crystallography and to look differently at the dynamics. The three main classes of aperiodic crystals, modulated phases, incommensurate composites, and quasicrystals are treated from a unified point of view, which stresses the similarities of the various systems.
Keywords: solid state matter, aperiodic crystals, organic compounds, anorganic compounds, minerals, metallic alloys, superspace, crystallography, theory of condensed matter Table of Contents
Preface
1.
INTRODUCTION
2.
DESCRIPTION AND SYMMETRY OF APERIODIC CRYSTALS
3.
MATHEMATICAL MODELS
4.
STRUCTURE
5.
ORIGIN AND STABILITY
6.
PHYSICAL PROPERTIES
7.
OTHER TOPICS
Appendix
Bibliography
Index
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